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1: 33.22 Particle Scattering and Atomic and Molecular Spectra
At positive energies E > 0 , ρ 0 , and:
Attractive potentials: Z 1 Z 2 < 0 , η < 0 .
Repulsive potentials: Z 1 Z 2 > 0 , η > 0 .
R = m e c α 2 / ( 2 ) . … Both variable sets may be used for attractive and repulsive potentials: the ( ϵ , r ) set cannot be used for a zero potential because this would imply r = 0 for all s , and the ( η , ρ ) set cannot be used for zero energy E because this would imply ρ = 0 always. … The penetrability of repulsive Coulomb potential barriers is normally expressed in terms of the quantity ρ / ( F 2 ( η , ρ ) + G 2 ( η , ρ ) ) (Mott and Massey (1956, pp. 63–65)). …
2: Bibliography Y
  • F. L. Yost, J. A. Wheeler, and G. Breit (1936) Coulomb wave functions in repulsive fields. Phys. Rev. 49 (2), pp. 174–189.
  • 3: 18.40 Methods of Computation
    Equation (18.40.7) provides step-histogram approximations to a x d μ ( x ) , as shown in Figure 18.40.1 for N = 12 and 120 , shown here for the repulsive Coulomb–Pollaczek OP’s of Figure 18.39.2, with the parameters as listed therein.
    See accompanying text
    Figure 18.40.1: Histogram approximations to the Repulsive Coulomb–Pollaczek, RCP, weight function integrated over [ 1 , x ) , see Figure 18.39.2 for an exact result, for Z = + 1 , shown for N = 12 and N = 120 . Magnify
    The example chosen is inversion from the α n , β n for the weight function for the repulsive Coulomb–Pollaczek, RCP, polynomials of (18.39.50). … Further, exponential convergence in N , via the Derivative Rule, rather than the power-law convergence of the histogram methods, is found for the inversion of Gegenbauer, Attractive, as well as Repulsive, Coulomb–Pollaczek, and Hermite weights and zeros to approximate w ( x ) for these OP systems on x [ 1 , 1 ] and ( , ) respectively, Reinhardt (2018), and Reinhardt (2021b), Reinhardt (2021a). …
    4: 33.1 Special Notation
    The main functions treated in this chapter are first the Coulomb radial functions F ( η , ρ ) , G ( η , ρ ) , H ± ( η , ρ ) (Sommerfeld (1928)), which are used in the case of repulsive Coulomb interactions, and secondly the functions f ( ϵ , ; r ) , h ( ϵ , ; r ) , s ( ϵ , ; r ) , c ( ϵ , ; r ) (Seaton (1982, 2002a)), which are used in the case of attractive Coulomb interactions. …
    5: 18.39 Applications in the Physical Sciences
    As in this subsection both positive (repulsive) and negative (attractive) Coulomb interactions are discussed, the prefactor of Z / r in (18.39.43) has been set to + 1 , rather than the 1 of (18.39.28) implying that Z < 0 is an attractive interaction, Z > 0 being repulsive. … For Z > 0 these are the repulsive CP OP’s with x [ 1 , 1 ] corresponding to the continuous spectrum of ( Z ) , ϵ ( 0 , ) , and for Z < 0 we have the attractive CP OP’s, where the spectrum is complemented by the infinite set of bound state eigenvalues for fixed l . … Given that a = b in both the attractive and repulsive cases, the expression for the absolutely continuous, x [ 1 , 1 ] , part of the function of (18.35.6) may be simplified: … The weight functions for both the attractive and repulsive cases are now unit normalized, see Bank and Ismail (1985), and Ismail (2009). …
    6: Bibliography O
  • M. K. Ong (1986) A closed form solution of the s -wave Bethe-Goldstone equation with an infinite repulsive core. J. Math. Phys. 27 (4), pp. 1154–1158.
  • 7: Bibliography R
  • J. Rys, M. Dupuis, and H. F. King (1983) Computation of electron repulsion integrals using the Rys quadrature method. J. Comput. Chem. 4 (2), pp. 154–175.
  • 8: Bibliography H
  • F. E. Harris (2002) Analytic evaluation of two-center STO electron repulsion integrals via ellipsoidal expansion. Internat. J. Quantum Chem. 88 (6), pp. 701–734.
  • 9: Bibliography B
  • J. C. Bronski, L. D. Carr, B. Deconinck, J. N. Kutz, and K. Promislow (2001) Stability of repulsive Bose-Einstein condensates in a periodic potential. Phys. Rev. E (3) 63 (036612), pp. 1–11.
  • 10: Bibliography C
  • L. D. Carr, C. W. Clark, and W. P. Reinhardt (2000) Stationary solutions of the one-dimensional nonlinear Schrödinger equation. I. Case of repulsive nonlinearity. Phys. Rev. A 62 (063610), pp. 1–10.