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33 Coulomb FunctionsVariables \rho,\eta

§33.2 Definitions and Basic Properties

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§33.2(i) Coulomb Wave Equation

This differential equation has a regular singularity at \rho=0 with indices \ell+1 and -\ell, and an irregular singularity of rank 1 at \rho=\infty (§§2.7(i), 2.7(ii)). There are two turning points, that is, points at which \ifrac{{d}^{2}w}{{d\rho}^{2}}=02.8(i)). The outer one is given by

33.2.2\mathop{\rho_{{\mathrm{tp}}}\/}\nolimits\!\left(\eta,\ell\right)=\eta+(\eta^{2%
}+\ell(\ell+1))^{{1/2}}.

§33.2(ii) Regular Solution \mathop{F_{{\ell}}\/}\nolimits\!\left(\eta,\rho\right)

The function \mathop{F_{{\ell}}\/}\nolimits\!\left(\eta,\rho\right) is recessive (§2.7(iii)) at \rho=0, and is defined by

or equivalently

where \mathop{M_{{\kappa,\mu}}\/}\nolimits\!\left(z\right) and \mathop{M\/}\nolimits\!\left(a,b,z\right) are defined in §§13.14(i) and 13.2(i), and

33.2.5\mathop{C_{{\ell}}\/}\nolimits\!\left(\eta\right)=\frac{2^{\ell}e^{{-\pi\eta/2%
}}|\mathop{\Gamma\/}\nolimits\!\left(\ell+1+i\eta\right)|}{(2\ell+1)!}.

The choice of ambiguous signs in (33.2.3) and (33.2.4) is immaterial, provided that either all upper signs are taken, or all lower signs are taken. This is a consequence of Kummer’s transformation (§13.2(vii)).

\mathop{F_{{\ell}}\/}\nolimits\!\left(\eta,\rho\right) is a real and analytic function of \rho on the open interval 0<\rho<\infty, and also an analytic function of \eta when -\infty<\eta<\infty.

The normalizing constant \mathop{C_{{\ell}}\/}\nolimits\!\left(\eta\right) is always positive, and has the alternative form

§33.2(iii) Irregular Solutions \mathop{G_{{\ell}}\/}\nolimits\!\left(\eta,\rho\right),\mathop{{H^{{\pm}}_{{%
\ell}}}\/}\nolimits\!\left(\eta,\rho\right)

The functions \mathop{{H^{{\pm}}_{{\ell}}}\/}\nolimits\!\left(\eta,\rho\right) are defined by

or equivalently

where \mathop{W_{{\kappa,\mu}}\/}\nolimits\!\left(z\right), \mathop{U\/}\nolimits\!\left(a,b,z\right) are defined in §§13.14(i) and 13.2(i),

33.2.9\mathop{{\theta_{{\ell}}}\/}\nolimits\!\left(\eta,\rho\right)=\rho-\eta\mathop%
{\ln\/}\nolimits\!\left(2\rho\right)-\tfrac{1}{2}\ell\pi+\mathop{{\sigma_{{%
\ell}}}\/}\nolimits\!\left(\eta\right),

and

33.2.10\mathop{{\sigma_{{\ell}}}\/}\nolimits\!\left(\eta\right)=\mathop{\mathrm{ph}\/%
}\nolimits\mathop{\Gamma\/}\nolimits\!\left(\ell+1+i\eta\right),

the branch of the phase in (33.2.10) being zero when \eta=0 and continuous elsewhere. \mathop{{\sigma_{{\ell}}}\/}\nolimits\!\left(\eta\right) is the Coulomb phase shift.

\mathop{{H^{{+}}_{{\ell}}}\/}\nolimits\!\left(\eta,\rho\right) and \mathop{{H^{{-}}_{{\ell}}}\/}\nolimits\!\left(\eta,\rho\right) are complex conjugates, and their real and imaginary parts are given by

As in the case of \mathop{F_{{\ell}}\/}\nolimits\!\left(\eta,\rho\right), the solutions \mathop{{H^{{\pm}}_{{\ell}}}\/}\nolimits\!\left(\eta,\rho\right) and \mathop{G_{{\ell}}\/}\nolimits\!\left(\eta,\rho\right) are analytic functions of \rho when 0<\rho<\infty. Also, e^{{\mp i\mathop{{\sigma_{{\ell}}}\/}\nolimits\!\left(\eta\right)}}\mathop{{H^%
{{\pm}}_{{\ell}}}\/}\nolimits\!\left(\eta,\rho\right) are analytic functions of \eta when -\infty<\eta<\infty.

§33.2(iv) Wronskians and Cross-Product