# §33.2 Definitions and Basic Properties

## §33.2(i) Coulomb Wave Equation

 33.2.1 $\frac{{\mathrm{d}}^{2}w}{{\mathrm{d}\rho}^{2}}+\left(1-\frac{2\eta}{\rho}-% \frac{\ell(\ell+1)}{\rho^{2}}\right)w=0,$ $\ell=0,1,2,\dots$.

This differential equation has a regular singularity at $\rho=0$ with indices $\ell+1$ and $-\ell$, and an irregular singularity of rank 1 at $\rho=\infty$ (§§2.7(i), 2.7(ii)). There are two turning points, that is, points at which $\ifrac{{\mathrm{d}}^{2}w}{{\mathrm{d}\rho}^{2}}=0$2.8(i)). The outer one is given by

 33.2.2 $\rho_{\mathrm{tp}}\left(\eta,\ell\right)=\eta+(\eta^{2}+\ell(\ell+1))^{1/2}.$ ⓘ Defines: $\rho_{\mathrm{tp}}\left(\NVar{\eta},\NVar{\ell}\right)$: outer turning point for Coulomb radial functions Symbols: $\ell$: nonnegative integer and $\eta$: real parameter Referenced by: §33.12(i), §33.14(i) Permalink: http://dlmf.nist.gov/33.2.E2 Encodings: TeX, pMML, png See also: Annotations for 33.2(i), 33.2 and 33

## §33.2(ii) Regular Solution $F_{\ell}\left(\eta,\rho\right)$

The function $F_{\ell}\left(\eta,\rho\right)$ is recessive (§2.7(iii)) at $\rho=0$, and is defined by

 33.2.3 $F_{\ell}\left(\eta,\rho\right)=C_{\ell}\left(\eta\right)2^{-\ell-1}(\mp\mathrm% {i})^{\ell+1}M_{\pm\mathrm{i}\eta,\ell+\frac{1}{2}}\left(\pm 2\mathrm{i}\rho% \right),$ ⓘ Defines: $F_{\NVar{\ell}}\left(\NVar{\eta},\NVar{\rho}\right)$: regular Coulomb radial function Symbols: $C_{\NVar{\ell}}\left(\NVar{\eta}\right)$: normalizing constant for Coulomb radial functions, $M_{\NVar{\kappa},\NVar{\mu}}\left(\NVar{z}\right)$: Whittaker confluent hypergeometric function, $\ell$: nonnegative integer, $\rho$: nonnegative real variable and $\eta$: real parameter Referenced by: §13.18(vi), §33.2(ii) Permalink: http://dlmf.nist.gov/33.2.E3 Encodings: TeX, pMML, png See also: Annotations for 33.2(ii), 33.2 and 33

or equivalently

 33.2.4 $F_{\ell}\left(\eta,\rho\right)=C_{\ell}\left(\eta\right)\rho^{\ell+1}e^{\mp% \mathrm{i}\rho}M\left(\ell+1\mp\mathrm{i}\eta,2\ell+2,\pm 2\mathrm{i}\rho% \right),$

where $M_{\kappa,\mu}\left(z\right)$ and $M\left(a,b,z\right)$ are defined in §§13.14(i) and 13.2(i), and

 33.2.5 $C_{\ell}\left(\eta\right)=\frac{2^{\ell}e^{-\pi\eta/2}|\Gamma\left(\ell+1+% \mathrm{i}\eta\right)|}{(2\ell+1)!}.$ ⓘ Defines: $C_{\NVar{\ell}}\left(\NVar{\eta}\right)$: normalizing constant for Coulomb radial functions Symbols: $\Gamma\left(\NVar{z}\right)$: gamma function, $\pi$: the ratio of the circumference of a circle to its diameter, $\mathrm{e}$: base of natural logarithm, $!$: factorial (as in $n!$), $\ell$: nonnegative integer and $\eta$: real parameter A&S Ref: 14.1.7 Referenced by: §33.10(ii), §33.10(iii), §33.16(i) Permalink: http://dlmf.nist.gov/33.2.E5 Encodings: TeX, pMML, png See also: Annotations for 33.2(ii), 33.2 and 33

The choice of ambiguous signs in (33.2.3) and (33.2.4) is immaterial, provided that either all upper signs are taken, or all lower signs are taken. This is a consequence of Kummer’s transformation (§13.2(vii)).

$F_{\ell}\left(\eta,\rho\right)$ is a real and analytic function of $\rho$ on the open interval $0<\rho<\infty$, and also an analytic function of $\eta$ when $-\infty<\eta<\infty$.

The normalizing constant $C_{\ell}\left(\eta\right)$ is always positive, and has the alternative form

 33.2.6 $C_{\ell}\left(\eta\right)=\dfrac{2^{\ell}\left((2\pi\eta/(e^{2\pi\eta}-1))% \prod_{k=1}^{\ell}(\eta^{2}+k^{2})\right)^{\ifrac{1}{2}}}{(2\ell+1)!}.$

## §33.2(iii) Irregular Solutions $G_{\ell}\left(\eta,\rho\right),{H^{\pm}_{\ell}}\left(\eta,\rho\right)$

The functions ${H^{\pm}_{\ell}}\left(\eta,\rho\right)$ are defined by

 33.2.7 ${H^{\pm}_{\ell}}\left(\eta,\rho\right)=(\mp\mathrm{i})^{\ell}e^{(\pi\eta/2)\pm% \mathrm{i}{\sigma_{\ell}}\left(\eta\right)}W_{\mp\mathrm{i}\eta,\ell+\frac{1}{% 2}}\left(\mp 2\mathrm{i}\rho\right),$ ⓘ Defines: ${H^{\NVar{\pm}}_{\NVar{\ell}}}\left(\NVar{\eta},\NVar{\rho}\right)$: irregular Coulomb radial functions Symbols: ${\sigma_{\NVar{\ell}}}\left(\NVar{\eta}\right)$: Coulomb phase shift, $W_{\NVar{\kappa},\NVar{\mu}}\left(\NVar{z}\right)$: Whittaker confluent hypergeometric function, $\pi$: the ratio of the circumference of a circle to its diameter, $\mathrm{e}$: base of natural logarithm, $\ell$: nonnegative integer, $\rho$: nonnegative real variable and $\eta$: real parameter Referenced by: §13.18(vi), §33.23(vi) Permalink: http://dlmf.nist.gov/33.2.E7 Encodings: TeX, pMML, png See also: Annotations for 33.2(iii), 33.2 and 33

or equivalently

 33.2.8 ${H^{\pm}_{\ell}}\left(\eta,\rho\right)=e^{\pm\mathrm{i}{\theta_{\ell}}\left(% \eta,\rho\right)}(\mp 2\mathrm{i}\rho)^{\ell+1\pm\mathrm{i}\eta}U\left(\ell+1% \pm\mathrm{i}\eta,2\ell+2,\mp 2\mathrm{i}\rho\right),$

where $W_{\kappa,\mu}\left(z\right)$, $U\left(a,b,z\right)$ are defined in §§13.14(i) and 13.2(i),

 33.2.9 ${\theta_{\ell}}\left(\eta,\rho\right)=\rho-\eta\ln\left(2\rho\right)-\tfrac{1}% {2}\ell\pi+{\sigma_{\ell}}\left(\eta\right),$ ⓘ Defines: ${\theta_{\NVar{\ell}}}\left(\NVar{\eta},\NVar{\rho}\right)$: phase of Coulomb functions Symbols: ${\sigma_{\NVar{\ell}}}\left(\NVar{\eta}\right)$: Coulomb phase shift, $\pi$: the ratio of the circumference of a circle to its diameter, $\ln\NVar{z}$: principal branch of logarithm function, $\ell$: nonnegative integer, $\rho$: nonnegative real variable and $\eta$: real parameter A&S Ref: 14.5.5 Referenced by: §33.10(i), §33.11 Permalink: http://dlmf.nist.gov/33.2.E9 Encodings: TeX, pMML, png See also: Annotations for 33.2(iii), 33.2 and 33

and

 33.2.10 ${\sigma_{\ell}}\left(\eta\right)=\operatorname{ph}\Gamma\left(\ell+1+\mathrm{i% }\eta\right),$ ⓘ Defines: ${\sigma_{\NVar{\ell}}}\left(\NVar{\eta}\right)$: Coulomb phase shift Symbols: $\Gamma\left(\NVar{z}\right)$: gamma function, $\operatorname{ph}$: phase, $\ell$: nonnegative integer and $\eta$: real parameter A&S Ref: 14.5.6 Referenced by: §33.10(ii), §33.10(iii), §33.13, §33.2(iii), §33.25, §5.20 Permalink: http://dlmf.nist.gov/33.2.E10 Encodings: TeX, pMML, png See also: Annotations for 33.2(iii), 33.2 and 33

the branch of the phase in (33.2.10) being zero when $\eta=0$ and continuous elsewhere. ${\sigma_{\ell}}\left(\eta\right)$ is the Coulomb phase shift.

${H^{+}_{\ell}}\left(\eta,\rho\right)$ and ${H^{-}_{\ell}}\left(\eta,\rho\right)$ are complex conjugates, and their real and imaginary parts are given by

 33.2.11 $\displaystyle{H^{+}_{\ell}}\left(\eta,\rho\right)$ $\displaystyle=G_{\ell}\left(\eta,\rho\right)+\mathrm{i}F_{\ell}\left(\eta,\rho% \right),$ $\displaystyle{H^{-}_{\ell}}\left(\eta,\rho\right)$ $\displaystyle=G_{\ell}\left(\eta,\rho\right)-\mathrm{i}F_{\ell}\left(\eta,\rho% \right).$ ⓘ Defines: $G_{\NVar{\ell}}\left(\NVar{\eta},\NVar{\rho}\right)$: irregular Coulomb radial function Symbols: ${H^{\NVar{\pm}}_{\NVar{\ell}}}\left(\NVar{\eta},\NVar{\rho}\right)$: irregular Coulomb radial functions, $F_{\NVar{\ell}}\left(\NVar{\eta},\NVar{\rho}\right)$: regular Coulomb radial function, $\ell$: nonnegative integer, $\rho$: nonnegative real variable and $\eta$: real parameter Permalink: http://dlmf.nist.gov/33.2.E11 Encodings: TeX, TeX, pMML, pMML, png, png See also: Annotations for 33.2(iii), 33.2 and 33

As in the case of $F_{\ell}\left(\eta,\rho\right)$, the solutions ${H^{\pm}_{\ell}}\left(\eta,\rho\right)$ and $G_{\ell}\left(\eta,\rho\right)$ are analytic functions of $\rho$ when $0<\rho<\infty$. Also, $e^{\mp\mathrm{i}{\sigma_{\ell}}\left(\eta\right)}{H^{\pm}_{\ell}}\left(\eta,% \rho\right)$ are analytic functions of $\eta$ when $-\infty<\eta<\infty$.

## §33.2(iv) Wronskians and Cross-Product

With arguments $\eta,\rho$ suppressed,

 33.2.12 $\mathscr{W}\left\{G_{\ell},F_{\ell}\right\}=\mathscr{W}\left\{{H^{\pm}_{\ell}}% ,F_{\ell}\right\}=1.$
 33.2.13 $F_{\ell-1}G_{\ell}-F_{\ell}G_{\ell-1}=\ell/(\ell^{2}+\eta^{2})^{1/2},$ $\ell\geq 1$.